SDN0013.05 – Properties of Liquid Nitrogen

Molecular weight

28.014

 

 

Gas density

4.415 g/l at 77 K

 

1.250 g/l at 273 K

 

 

Liquid density 

0.808 kg/l at 77 K

 

 

Vapor / liquid volume ratio

646:1 (vapor at STP = 760 mm, 273 K)

 

 

Enthalpy of vaporization

198.8 J/g (760 mm, 77.35 K)

 

= 160 kJ/l (760 mm, 77.35 K)

 

= 44.6 W-hr/l

 

 

Enthalpy of fusion

25.3 J/g (93.9 mm, 63.15 K = triple point)

 

 

Heat capacity of liquid

2.042 J/g-K (77.35 K)

 

 

Heat capacity of vapor

1.341 J/g-K (77.35 K)

 

1.072 J/g-K (100 K)

 

1.046 J/g-K (200 K)

 

1.041 J/g-K (300 K)

 

 

 

238 J/g (77 – 300 K, approximate)

 

= 192 kJ/l (liquid)

 

= 53.4 W-hr/l

 

 

Energy to vaporize liquid and heat gas to 300 K

437 J/g

 

= 352 kJ/l

 

= 98 W-h/l

 

 

Boiling Point

77.35 K (760 mm)

 

76.67 K (700 mm; Tucson)

 

73.00 K (440 mm; Mauna Kea)

 

 

An empirical expression for the vapor pressure is:

Log (P) = 6.49594 – 255.821/(T – 6.600)


 

Plots of this relation follow. The critical temperature (Tc) = 126.2 K; the triple point (Tp) is marked on the plots with a dot at 63.15 K.

 



 

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